Nickel-Catalyzed Reductive Alkene Cross-Dialkylation with Unactivated Alkyl Electrophiles.
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DOI: 10.1021/acs.orglett.3c04207
Abstract: A Ni-catalyzed reductive dialkylation of 8-aminoquinoline-tethered aliphatic alkenes with two unactivated alkyl electrophiles is disclosed here. Key to the development of this transformation is the combination of primary alkyl (pseudo)halides and secondary alkyl iodides that… read more here.
Keywords: unactivated alkyl; alkyl electrophiles; dialkylation; reductive alkene ... See more keywords