Reductive Aromatization/Dearomatization and Elimination Reactions to Access Conjugated Polycyclic Hydrocarbons, Heteroacenes, and Cumulenes.
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DOI: 10.1002/cplu.201700168
Abstract: Acenes, heteroacenes, conjugated polycyclic hydrocarbons, and polycyclic aromatic hydrocarbons (collectively referred to in this review as conjugated polycyclic molecules, CPMs) have fascinated chemists since they were first isolated and synthesized in the mid 19th century. Most… read more here.
Keywords: conjugated polycyclic; aromatization; polycyclic hydrocarbons; reductive aromatization ... See more keywords
The reductive aromatization of naphthalene diimide: a versatile platform for 2,7-diazapyrenes.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc01937a
Abstract: The reductive aromatization of naphthalene diimide provides tetrapivaloxy-2,7-diazapyrene, which serves as a versatile platform toward peripherally substituted 2,7-diazapyrenes. Time-resolved microwave conductivity measurements demonstrated that the intrinsic electron mobility of 2,7-diazapyrene is significantly higher than that… read more here.
Keywords: naphthalene diimide; aromatization naphthalene; reductive aromatization; versatile platform ... See more keywords