Reductive Carbonylation of Nitroarenes Using a Heterogenized Phen-Pd Catalyst.
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DOI: 10.1021/acs.inorgchem.1c03313
Abstract: The reductive carbonylation of nitroarenes in the presence of MeOH and CO(g) is one of the interesting alternative routes without utilizing toxic phosgene and corrosive HCl generation for the synthesis of industrially useful carbamate compounds… read more here.
Keywords: catalyst; reductive carbonylation; phen; carbonylation nitroarenes ... See more keywords
Insights into the ligand effects of rhodium catalysts toward reductive carbonylation of methanol to ethanol
Sign Up to like & getrecommendations! Published in 2017 at "RSC Advances"
DOI: 10.1039/c7ra10739k
Abstract: Methanol reductive carbonylation to ethanol catalyzed by diphosphine ligand modified Rh-based catalysts has been studied. All the catalysts show ligand effects toward the turnover frequency and selectivity. Four Rh–diphosphine complexes were isolated and single crystals… read more here.
Keywords: catalysts toward; ligand effects; reductive carbonylation; effects rhodium ... See more keywords