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1
Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00270
Abstract: A range of medium-sized cyclic ethers (5 to 11 membered) have been effectively synthesized through intramolecular reductive coupling of dialdehydes initiated by 50 ppm to 0.5% of AgNTf2 with hydrosilane at 25 °C. The catalytic…
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Keywords:
reductive cross;
cross coupling;
coupling aldehydes;
catalyzed reductive ... See more keywords
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1
Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01801
Abstract: We report an enantioselective reductive cross coupling of electron-deficient olefins. Using a visible-light-driven cooperative photoredox and chiral Brønsted acid-catalyzed reaction with a Hantzsch ester as the terminal reductant, various cyclic and acyclic enones with 2-vinylpyridines…
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Keywords:
electron deficient;
coupling electron;
reductive cross;
cross coupling ... See more keywords
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1
Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01954
Abstract: A nickel-catalyzed C-S reductive cross-coupling of alkyl halides with arylthiosilanes for producing alkyl aryl thioethers is developed. This reaction is initiated by umpolung transformations of arylthiosilanes followed by C-S reductive cross-coupling with alkyl halides to…
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Keywords:
coupling alkyl;
reductive cross;
cross coupling;
nickel catalyzed ... See more keywords
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2
Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c00185
Abstract: Herein, a nickel catalysis system for desulfonylative C(sp2)-C(sp2) reductive cross-coupling reactions of aryl sulfone derivatives with a range of aryl bromides has been established to form diverse biaryl compounds. The complex Ar-Ni(II)-SO2CF3 bearing a phosphine…
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Keywords:
reductive cross;
cross coupling;
nickel catalyzed;
catalyzed desulfonylative ... See more keywords
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0
Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b01014
Abstract: A nickel-catalyzed reductive cross-coupling of alkylpyridinium salts and aryl bromides has been developed using Mn as the reductant. Both primary and secondary alkylpyridinium salts can be used, and high functional group and heterocycle tolerance is…
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Keywords:
aryl bromides;
reductive cross;
alkylpyridinium;
alkylpyridinium salts ... See more keywords
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1
Published in 2022 at "ACS catalysis"
DOI: 10.1021/acscatal.2c03033
Abstract: Nickel-catalyzed reductive cross-electrophile coupling reactions are becoming increasingly important in organic synthesis, but application at scale is limited by three interconnected challenges: a reliance on amide solvents (complicated workup, regulated), the generation of stoichiometric Zn…
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Keywords:
cell;
reductive cross;
catalyst;
electrochemistry ... See more keywords
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1
Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c12424
Abstract: Chiral phosphine-containing skeletons are important motifs in bioactive natural products, pharmaceuticals, chiral catalysts, and ligands. Herein, we report a general and modular platform to access chiral α-aryl phosphorus compounds via a Ni/photoredox-catalyzed enantioconvergent reductive cross-coupling…
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Keywords:
access chiral;
cross coupling;
photoredox catalyzed;
reductive cross ... See more keywords
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2
Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c01487
Abstract: An organophosphorus-catalyzed C-N bond-forming reductive coupling of nitroalkanes with arylboronic acids and esters is reported. The method shows excellent chemoselectivity for the nitro/boronic acid substrate pair, allowing the synthesis of N-(hetero)arylamines rich in functionalization. The…
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Keywords:
boronic acids;
enabling reductive;
coupling nitroalkanes;
reductive cross ... See more keywords
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0
Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b03448
Abstract: A Ni-catalyzed reductive cross-coupling of styrenyl aziridines with aryl iodides is reported. This reaction proceeds by a stereoconvergent mechanism and is thus amenable to asymmetric catalysis using a chiral bioxazoline ligand for Ni. The process…
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Keywords:
reductive cross;
coupling styrenyl;
styrenyl aziridines;
nickel catalyzed ... See more keywords
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Published in 2021 at "Organic Chemistry Frontiers"
DOI: 10.1039/d1qo00759a
Abstract: Palladium-catalyzed direct reductive cross-coupling of aryltrimethylammonium salts with aryl bromides proceeded efficiently in a one-pot manner in the presence of Mg turnings, LiCl, and TMEDA in THF to afford the corresponding biaryl compounds.
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Keywords:
reductive cross;
coupling aryltrimethylammonium;
palladium catalyzed;
catalyzed direct ... See more keywords
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Published in 2017 at "Synthesis"
DOI: 10.1055/s-0036-1588132
Abstract: The use of pyridine as the sole ligand for the reductive vinylation of unactivated secondary alkyl halides under Ni-catalyzed conditions has been developed. Both alkyl- and aryl-substituted vinyl bromides are suitable, in which alkyl-decorated α-alkenyl…
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Keywords:
alkyl halides;
reductive cross;
vinyl bromides;
catalyzed reductive ... See more keywords