Ni-Catalyzed Reductive Cyanation of Aryl Halides and Phenol Derivatives via Transnitrilation.
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DOI: 10.1021/jacs.9b11208
Abstract: Herein, we report a Ni-catalyzed reductive coupling for the synthesis of benzonitriles from aryl (pseudo)halides and an electrophilic cyanating reagent, 2-methyl-2-phenyl malononitrile (MPMN). MPMN is a bench-stable, carbon-bound electrophilic CN reagent that does not release… read more here.
Keywords: catalyzed reductive; cyanation aryl; aryl halides; reductive cyanation ... See more keywords