Cascade Reductive Etherification of Bioderived Aldehydes over Zr-Based Catalysts.
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DOI: 10.1002/cssc.201701275
Abstract: An efficient one-pot catalytic cascade sequence has been developed for the production of value-added ethers from bioderived aldehydes. Etherification of 5-(hydroxymethyl)furfural with different aliphatic alcohols over acidic Zr-montmorillonite (Zr-Mont) catalyst produced a mixture of 5-(alkoxymethyl)furfural… read more here.
Keywords: alkoxymethyl furan; bioderived aldehydes; spectroscopy; etherification ... See more keywords
Synthesis of Ethyl-4-ethoxy Pentanoate by Reductive Etherification of Ethyl Levulinate in Ethanol on Pd/SiO2 -C Catalysts.
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DOI: 10.1002/cssc.201801624
Abstract: The synthesis of biomass-derived ethers to be used as biofuels or biofuel additives has attracted much attention. Following the recently reported synthesis of etherified ester ethyl-4-ethoxy pentanoate (EEP) from γ-valerolactone (GVL) in ethanol catalyzed by… read more here.
Keywords: ethyl; etherification ethyl; ethoxy pentanoate; pentanoate ... See more keywords
Reductive Etherification via Anion-Binding Catalysis.
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DOI: 10.1021/jacs.7b05832
Abstract: Reductive condensations of alcohols with aldehydes/ketones to generate ethers are catalyzed by a readily accessible thiourea organocatalyst that operates in combination with HCl. 1,1,3,3-tetramethyldisiloxane serves as a convenient reducing reagent. This strategy is applicable to… read more here.
Keywords: reductive etherification; etherification via; binding catalysis; via anion ... See more keywords
Single-phase catalysis for reductive etherification of diesel bioblendstocks
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DOI: 10.1039/d0gc00939c
Abstract: Reductive etherification is a promising catalytic chemistry for coupling biomass derived alcohols and ketones to produce branched ethers that can be used as high cetane, low sooting blendstocks for diesel fuel applications. Previous catalyst materials… read more here.
Keywords: catalyst; single phase; chemistry; reductive etherification ... See more keywords