Ni-Catalyzed Reductive Fluoroalkylacylation of Alkynes for the Steroselective Synthesis of Fluoroalkylated Enones.
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DOI: 10.1021/acs.orglett.2c02464
Abstract: A Ni-catalyzed three-component reductive fluoroalkylacylation of alkynes with fluoroalkyl halides and acyl chlorides is presented. This dicarbofunctionalization provides an efficient method for the synthesis of fluoroalkyl-incorporated enones under mild conditions with high yields and excellent… read more here.
Keywords: fluoroalkylacylation alkynes; synthesis; catalyzed reductive; alkynes steroselective ... See more keywords