Reductive Halogenation Reactions: Selective Synthesis of Unsymmetrical α-Haloketones.
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DOI: 10.1021/acs.orglett.9b02324
Abstract: A method for the selective synthesis of unsymmetrical α-haloketones has been developed. The key transformation is a triphenylphosphine oxide catalyzed reductive halogenation of an α,β-unsaturated ketone in which trichlorosilane is the reducing reagent and an… read more here.
Keywords: selective synthesis; reductive halogenation; synthesis unsymmetrical; unsymmetrical haloketones ... See more keywords