Alcohol Synthesis by Cobalt-Catalyzed Visible-Light-Driven Reductive Hydroformylation.
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DOI: 10.1021/jacs.2c07745
Abstract: A cobalt-catalyzed reductive hydroformylation of terminal and 1,1-disubstituted alkenes is described. One-carbon homologated alcohols were synthesized directly from CO and H2, affording anti-Markovnikov products (34-87% yield) with exclusive regiocontrol (linear/branch >99:1) for minimally functionalized alkenes.… read more here.
Keywords: cobalt catalyzed; alcohol synthesis; cobalt; hydroformylation ... See more keywords