Synthesis, Characterization and Electrochemical Reductive Properties of Complexes [Fe 2 (CO) 4 (κ 2 ‐P Ph 2 N R 2 )( µ ‐dithiolato)] Related to the H‐Cluster of [FeFe]‐H 2 ases
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DOI: 10.1002/ejic.202000824
Abstract: A series of dithiolate carbonyl diiron complexes with cyclic azadiphosphine, related to the active site of [FeFe]‐hydrogenases, has been prepared. Several combinations of diphosphines and dithiolate bridges have been examined in order to obtain information… read more here.
Keywords: synthesis characterization; properties complexes; characterization electrochemical; reductive properties ... See more keywords