Catalytic Reductive Vinylidene Transfer Reactions.
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DOI: 10.1021/jacs.7b05901
Abstract: Methylenecyclopropanes are important synthetic intermediates that possess strain energies exceeding those of saturated cyclopropanes by >10 kcal/mol. This report describes a catalytic reductive methylenecyclopropanation reaction of simple olefins, utilizing 1,1-dichloroalkenes as vinylidene precursors. The reaction… read more here.
Keywords: vinylidene transfer; reductive vinylidene; catalytic reductive; transfer reactions ... See more keywords