A Mechanistic Insight into the Ligand-Controlled Asymmetric Arylation of Aliphatic α-Amino Anion Equivalents: Origin of Regio- and Enantioselectivities.
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DOI: 10.1021/acs.inorgchem.7b00739
Abstract: The reaction mechanism and the origins of regio- and enantioselectivities for Pd-catalyzed asymmetric arylation of aliphatic α-amino anion equivalents were investigated computationally. The results indicate that the reaction proceeds via mainly six sequential steps: deprotonation… read more here.
Keywords: amino; arylation aliphatic; asymmetric arylation; regio enantioselectivities ... See more keywords