Ligand-controlled regiodivergent π-allyl palladium catalysis enables a switch between [3+2] and [3+3] cycloadditions.
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DOI: 10.1039/c9cc00611g
Abstract: Reported herein is the use of ligands to tune the regioselectivity and reactivity of palladium-catalyzed [3+2] and [3+3] cycloadditions. Diverse synthesis with vinylethylene carbonates (VECs) as well as free naphthols has been explored to construct… read more here.
Keywords: regiodivergent allyl; controlled regiodivergent; palladium catalysis; ligand controlled ... See more keywords