Mechanism and origins of ligand-controlled Pd(ii)-catalyzed regiodivergent carbonylation of alkynes.
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DOI: 10.1039/c9dt03294k
Abstract: Transition-metal-catalyzed carbonylation provides a useful approach to synthesize carbonyl-containing compounds and their derivatives. Controlling the regio-, chemo-, and stereoselectivity remains a significant challenge and is the key to the success of transformation. In the present… read more here.
Keywords: mechanism origins; mechanism; regiodivergent carbonylation; origins ligand ... See more keywords