Ruthenium-Catalyzed Ligand-Enabled Regiodivergent Difluoroallylation of Aryl C-H Bonds.
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DOI: 10.1021/acs.orglett.3c00873
Abstract: The gem-difluoroallyl group is a sought-after structural motif commonly found in pharmaceutical compounds. Despite its appeal, achieving a controlled synthesis of both α,α- and γ,γ-difluoroallylated compounds has proven to be a challenging task. This study… read more here.
Keywords: catalyzed ligand; ligand enabled; regiodivergent difluoroallylation; ruthenium catalyzed ... See more keywords