Ligand-Controlled Regiodivergent Silylation of Allylic Alcohols by Ni/Cu Catalysis for the Synthesis of Functionalized Allylsilanes.
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DOI: 10.1021/acs.orglett.9b03822
Abstract: The first Ni/Cu-catalyzed regiodivergent synthesis of allylsilanes directly from allylic alcohols through modulating the steric and electronic properties of the ligands on the nickel catalyst has been developed. Good yields and excellent selectivity were obtained… read more here.
Keywords: regiodivergent silylation; controlled regiodivergent; allylic alcohols; silylation allylic ... See more keywords