Controllable access to trifluoromethyl-containing indoles and indolines: palladium-catalyzed regioselective functionalization of unactivated alkenes with trifluoroacetimidoyl chlorides
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DOI: 10.1039/d2sc00546h
Abstract: The synthesis of diverse products from the same starting materials is always attractive in organic chemistry. Here, a palladium-catalyzed substrate-controlled regioselective functionalization of unactivated alkenes with trifluoroacetimidoyl chlorides has been developed, which provides a direct… read more here.
Keywords: functionalization unactivated; alkenes trifluoroacetimidoyl; palladium catalyzed; trifluoroacetimidoyl chlorides ... See more keywords
A Strategy for Regioselective B−H Functionalization of o-Carboranes via Base Metal Catalysis
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DOI: 10.1039/d3qo00621b
Abstract: Carboranes, a class of carbon-boron molecular clusters, own unique characteristics and are finding a variety of applications ranging from materials to medicine. In this connection, selective functionalization of o-carboranes has... read more here.
Keywords: via base; functionalization; carboranes via; functionalization carboranes ... See more keywords
Regioselective Functionalization of Arenes Using Iron Triflimide Catalysis
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DOI: 10.1055/s-0042-1751445
Abstract: Here we present our development of the super Lewis acid, iron(III) triflimide as an activating agent of N-halo- and N-thioaryl succinimides for the regioselective functionalization of arenes. We also describe how the iron(III)-catalyzed halogenation reactions… read more here.
Keywords: iron; one pot; iron iii; functionalization arenes ... See more keywords