Transition-metal-free regioselective hydroamination of styrenes with amino-heteroarenes.
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DOI: 10.1039/d2cc02781j
Abstract: The base-mediated anti-Markovnikov hydroamination of functionally varied styrenes with amino-substituted pyridine, quinoline, pyrimidine, pyrazine, and phenanthridine with excellent regioselectivity has been described. Double hydroamination was observed chemoselectively on the secondary amine, leaving the primary amine… read more here.
Keywords: regioselective hydroamination; metal free; transition metal; hydroamination ... See more keywords