Nickel-Catalyzed Regioselective 1,4-Hydroboration of N-Heteroarenes
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DOI: 10.1021/acscatal.8b01166
Abstract: Combinations of Ni(acac)2 with phosphine ligands were found to catalyze the regioselective hydroboration of N-heteroarenes with pinacolborane, affording N-borylated 1,4-reduction products. Preliminary mechanistic studies have focused on the isolation and study of potential intermediates in… read more here.
Keywords: regioselective hydroboration; catalyzed regioselective; hydroboration heteroarenes; nickel catalyzed ... See more keywords