Selenium-Catalyzed Regioselective Intermolecular Diamination of Dienes and Dienolate Derivatives.
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DOI: 10.1021/acs.orglett.4c03431
Abstract: We report a selenium-catalyzed diamination of dienes using sulfamates as a convenient nitrogen source. This reaction proceeds regioselectively for 1,2-addition at the less substituted alkene, without the need for a tethered diamine. We also report… read more here.
Keywords: selenium catalyzed; diamination dienes; catalyzed regioselective; regioselective intermolecular ... See more keywords
Rh(iii)-catalyzed regioselective intermolecular N-methylene Csp3–H bond carbenoid insertion† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc03802j
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Science"
DOI: 10.1039/c7sc03802j
Abstract: A Rh(iii)-catalyzed regioselective intermolecular carbenoid insertion into the N-methylene Csp3–H bond has been achieved via an outer-sphere pathway. read more here.
Keywords: methylene csp3; regioselective intermolecular; iii catalyzed; csp3 bond ... See more keywords