Catalytic 1,3-Proton Transfer in Alkenes Enabled by Fe═NR Bond Cooperativity: A Strategy for pKa-Dictated Regioselective Transposition of C═C Double Bonds.
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DOI: 10.1021/jacs.2c13350
Abstract: Transition metal catalyzed alkene double bond transposition usually involves metal hydride intermediates. Despite significant advances in the design of catalysts that dictate product selectivity, control over substrate selectivity is less advanced and transition metal catalysts… read more here.
Keywords: regioselective transposition; proton transfer; double bonds; transposition ... See more keywords