Computational study on C1- versus C3-regioselectivity in Pd(II)-catalyzed olefination/dearomatization of 2-naphthyl ureas
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DOI: 10.1016/j.mcat.2019.110540
Abstract: Abstract The regioselectivity in Pd(II)-catalyzed C H direct functionalization of C2-substituted naphthalenes has been a long-term issue in synthetic organic chemistry due to its existence of competitive reaction sites, including C1-, C3- and even C4-sites.… read more here.
Keywords: naphthyl ureas; dearomatization naphthyl; site; reaction ... See more keywords
Stereo- and Regioselectivity in Catalyzed Transformation of a 1,2-Disubstituted Vicinal Diol and the Corresponding Diketone by Wild Type and Laboratory Evolved Alcohol Dehydrogenases
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DOI: 10.1021/acscatal.8b01762
Abstract: ADH-A from Rhodococcus ruber DSM 44541 catalyzes the oxidation of (S)-1-phenylethanol 3000-fold more efficiently as compared with the 2-hydroxylated derivative (R)-phenylethane-1,2-diol. The enzyme is also highly selective for sec-alcohols with comparably low activities with the… read more here.
Keywords: regioselectivity catalyzed; diol; catalyzed transformation; alcohol ... See more keywords