Reinvestigation of the mechanism of polymerization of β-butyrolactone from 1,5,7-triazabicyclo[4.4.0]dec-5-ene
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DOI: 10.1039/c8py00206a
Abstract: The questionable mechanism initially proposed to explain how 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) allows us to ring-open β-lactones, such as β-butyrolactone (BL), is reinvestigated here. With the use of a trisubstituted β-lactone, i.e. (R,S)-benzylcarbonyl-3,3-dimethyl-2-oxetanone, and the association of… read more here.
Keywords: reinvestigation mechanism; mechanism polymerization; triazabicyclo dec; dec ene ... See more keywords