Cobalt(II) Ions Connecting [CoII4] Helicates into a 2-D Coordination Polymer Showing Slow Relaxation of the Magnetization.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b01640
Abstract: The reactions of cobalt(II) perchlorate with a diazine tetratopic helicand, H4L, in the presence of sodium carbonate afford two coordination polymers constructed from tetranuclear anionic helicates as building blocks: ∞3[Co4L3Na4(H2O)4]·4H2O (1) and ∞2[Co5L3Na2(H2O)9]·2.7H2O·DMF (2). The… read more here.
Keywords: relaxation magnetization; slow relaxation; cobalt; cobalt ions ... See more keywords
4f-π Molecular Hybrid Exhibiting Rich Conductive Phases and Slow Relaxation of Magnetization.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c03748
Abstract: Cooperation between single-molecule magnets and electrical conductivity holds promise for preparing high-density magnetic devices; however, there are only a few reports so far. Here we report a 4f-π-based molecular hybrid, k-(ET)5Dy(NCS)7(KCl)0.5 (1) (ET = bis(ethylenedithio)tetrathiafulvalene,… read more here.
Keywords: rich conductive; relaxation; relaxation magnetization; molecular hybrid ... See more keywords
Slow relaxation of the magnetization observed in mononuclear Ln-radical compounds with D4d geometry configurations.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c8dt03809k
Abstract: The combination of LnIII ions (GdIII, TbIII or DyIII) and a pyrazole nitronyl nitroxide radical results in three isomorphous complexes, namely, [Ln(hfac)3(NIT-Pyz)]2 (Ln = Gd(1), Tb(2), Dy(3); hfac = hexafluoroacetylacetone; NIT-Pyz = 2-{3-pyrazolyl}-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide). Single crystal… read more here.
Keywords: relaxation; relaxation magnetization; nit pyz; lniii ions ... See more keywords
Rationally assembled nonanuclear lanthanide clusters: Dy9 displays slow relaxation of magnetization and Tb9 serves as luminescent sensor for Fe3+, CrO42− and Cr2O72−
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c9nj04893f
Abstract: The utilization of a Schiff base ligand 2-((2-hydroxy-4-methoxy-benzylideneamino)methyl)phenol (H2L) afforded five nonanuclear lanthanide(iii) clusters. Dy9 displays slow relaxation of magnetization and Tb9 serves as luminescent sensor for Fe3+, CrO42− and Cr2O72−. read more here.
Keywords: displays slow; relaxation magnetization; nonanuclear lanthanide; dy9 displays ... See more keywords
Quasi-isotropic SMMs: slow relaxation of the magnetization in polynuclear CuII/MnII complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt04074j
Abstract: Three field induced SMMs built from quasi-isotropic cations like CuII and MnII have been characterized, showing that relatively large clusters with quasi-negligible D and different ground spin states, S = 3/2, 2 or 4, can… read more here.
Keywords: cuii mnii; relaxation magnetization; quasi isotropic; slow relaxation ... See more keywords
Slow Relaxation of the Magnetization in Anilato-Based Dy(III) 2D Lattices
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DOI: 10.3390/molecules26041190
Abstract: The search for two- and three-dimensional materials with slow relaxation of the magnetization (single-ion magnets, SIM and single-molecule magnets, SMM) has become a very active area in recent years. Here we show how it is… read more here.
Keywords: magnetization anilato; slow relaxation; relaxation magnetization;