Relay Catalysis of Fe and Co with Multi‐Active Sites for Specialized Division of Labor in Electrocatalytic Nitrate Reduction Reaction
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202403838
Abstract: Electrocatalytic nitrate reduction reaction (NO3RR) driven by renewable energy is a promising technology for the removal of nitrate‐containing wastewater. However, the sluggish kinetics resulted from the complex proton‐coupled electron transfer and various intermediates remain the… read more here.
Keywords: reduction reaction; relay catalysis; electrocatalytic nitrate; nitrate reduction ... See more keywords
Alloying of Cu with Ru Enabling the Relay Catalysis for Reduction of Nitrate to Ammonia
Sign Up to like & getrecommendations! Published in 2023 at "Advanced Materials"
DOI: 10.1002/adma.202202952
Abstract: Involving eight electron transfer process and multiple intermediates of nitrate (NO3−) reduction reaction leads to a sluggish kinetic and low Faradaic efficiency, therefore, it is essential to get an insight into the reaction mechanism to… read more here.
Keywords: reduction; highly efficient; relay catalysis; reduction no3 ... See more keywords
Bio‐Inspired Cu/Pd Bimetallic Catalysts Facilitating One‐Pot Relay Catalysis of Homo‐Couplings of Arylboronic Acids
Sign Up to like & getrecommendations! Published in 2024 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.7688
Abstract: Inspired by the multienzymatic relay catalysis in nature, herein, we reported a pioneering bio‐inspired Cu/Pd bimetallic composite microspheres (Cu/CMC@Pd/C) as a simple and efficient relay catalyst for the homo‐coupling of arylboronic acids. In this composite,… read more here.
Keywords: relay catalysis; relay; bio inspired; cmc ... See more keywords
Relay Catalysis Enabling the Value‐Added Upgrading of Plastic Wastes
Sign Up to like & getrecommendations! Published in 2025 at "ChemCatChem"
DOI: 10.1002/cctc.202500018
Abstract: Harnessing modern catalytic concepts to address the pressing challenge of plastic waste management has attracted significant interest from the scientific community in recent years. Notably, relay catalysis has emerged as a promising strategy, demonstrating substantial… read more here.
Keywords: value added; relay catalysis; catalysis enabling; plastic ... See more keywords
Relay catalysis of copper-magnesium catalyst on efficient valorization of glycerol to glycolic acid
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2021.132555
Abstract: Abstract The exploration of potential application of glycerol is of particular importance for solving the oversupply of glycerol as an unavoidable byproduct of biodiesel and affording profitable possibilities for sustainable biodiesel. Herein, we developed a… read more here.
Keywords: catalyst; relay catalysis; glycerol; acid ... See more keywords
Construction of Hydrodibenzo[b,d]furan Frameworks from Morita-Baylis-Hillman Carbonates of Isatins and o-Hydroxy Enones via Palladium and Brønsted Base Relay Catalysis.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c03689
Abstract: A cascade assembly between isatin-derived Morita-Baylis-Hillman carbonates and o-hydroxybenzylideneacetones has been developed under the relay catalysis of Pd(PPh3)4 and DBU, affording a spectrum of 1,2,3,4-tetrahydrodibenzo[b,d]furan architectures incorporating a spirooxindole motif in moderate to good yields… read more here.
Keywords: hillman carbonates; relay catalysis; morita baylis; baylis hillman ... See more keywords
Dual Rh(II)/Pd(0) Relay Catalysis Involving Sigmatropic Rearrangement Using N-Sulfonyl Triazoles and 2-Hydroxymethylallyl Carbonates.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02752
Abstract: Dual Rh(II)/Pd(0) relay catalysis of N-sulfonyl triazoles and 2-hydroxymethylallyl carbonates has been developed, which affords N-sulfonyl pyrrolidines in moderate to good yields with high diastereoselectivities. The reaction proceeds via a relay mechanism involving O-H insertion… read more here.
Keywords: triazoles hydroxymethylallyl; sulfonyl triazoles; hydroxymethylallyl carbonates; dual relay ... See more keywords
Synthesis of Oxa-spiro-bicyclo[2.1.1]hexane by Au/Sc Relay Catalysis.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.5c01542
Abstract: A new Au/Sc relay catalysis approach has been developed for the rapid construction of oxa-spiro-bicyclo[2.1.1]hexanes under mild conditions. This cascade reaction proceeds via a gold-catalyzed cycloisomerization followed by a Sc(OTf)3-catalyzed [3+2] cycloaddition with bicyclo[1.1.0]butanes (BCBs)… read more here.
Keywords: spiro bicyclo; oxa spiro; relay catalysis; bicyclo ... See more keywords
Synthesis of Indolizines via Reaction of 2-Substitued Azaarenes with Enals by an Amine-NHC Relay Catalysis.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b00566
Abstract: A metal-free catalytic strategy for the facile synthesis of biologically relevant molecular architectures indolizines and imidazopyridines has been developed. The process is promoted by amine and N-heterocyclic carbene (NHC) relay catalysis via Michael addition-[3 +… read more here.
Keywords: nhc relay; synthesis indolizines; indolizines via; relay catalysis ... See more keywords
Relay Catalysis of Rh (II) and Cobaloxime: Stereoselective Synthesis of Spiroindanones from N-Sulfonyl-1,2,3-triazoles.
Sign Up to like & getrecommendations! Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b03275
Abstract: A novel relay Rh (II)/cobaloxime (III) dual catalysis strategy has been developed for the stereoselective synthesis of indolyl spiroindanones from readily accessible N-sulfonyl-1,2,3-triazoles. This binary-catalyst system enables an aza-vinyl carbene initiated Pictet-Spengler-type cyclization and sequential… read more here.
Keywords: cobaloxime; sulfonyl triazoles; stereoselective synthesis; relay catalysis ... See more keywords
Asymmetric Rh(II)/Pd(0) Relay Catalysis: Synthesis of α-Quaternary Chiral β-Lactams through Enantioselective C–H Insertion/Diastereoselective Allylation of Diazoamides
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b01687
Abstract: A straightforward route toward construction of α-quaternary chiral β-lactam moiety via Rh(II)/Pd(0)-catalyzed stereoselective relay catalytic reaction is reported. This asymmetric dual relay catalysis involves Rh(II)-catalyzed enantioselective intramoluecular C–H insertions of α-diazoamides, and sequential Pd(0)-catalyzed diastereoselective… read more here.
Keywords: relay catalysis; relay; catalysis; asymmetric relay ... See more keywords