The Oxo-Wall Remains Intact: A Tetrahedrally Distorted Co(IV)-Oxo Complex.
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DOI: 10.1021/jacs.1c04919
Abstract: In this paper, we report the preparation, spectroscopic and theoretical characterization, and reactivity studies of a Co(IV)-oxo complex bearing an N4-macrocyclic coligand, 12-TBC (12-TBC = 1,4,7,10-tetrabenzyl-1,4,7,10-tetraazacyclododecane). On the basis of the ligand and the structure… read more here.
Keywords: oxo; oxo complex; remains intact; spectroscopy ... See more keywords