A Remarkable Influence of a Trifluoromethyl Group on the Reactions of β‐Mercaptoalcohols with Fluorinated α‐Bromoenones
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DOI: 10.1002/ejoc.201701752
Abstract: Isomeric fluorinated α‐bromoenones react with dinucleophilic β‐mercaptoalcohols in CH2Cl2 at room temperature in the presence of Et3N in a multistep process. Depending on the position of the CF3 group, different O,S‐heterocycles or non‐cyclic products were… read more here.
Keywords: group; trifluoromethyl group; influence trifluoromethyl; remarkable influence ... See more keywords
Remarkable Influence of α-SnWO4 Exposed Facets on Their Photocatalytic Performance for H2 and O2 Evolution Reactions
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DOI: 10.1021/acs.jpcc.0c06718
Abstract: A significant effect of the five major (121), (210), (111), (200), and (040) exposed facets obtained experimentally for orthorhombic α-SnWO4 material on its performance for photocatalytic water spl... read more here.
Keywords: exposed facets; facets photocatalytic; remarkable influence; influence snwo4 ... See more keywords
Remarkable Influence of Cobalt Catalysis on Epoxide Ring-Opening with Sulfoxonium Ylides
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DOI: 10.1055/s-0036-1588814
Abstract: Cobalt demonstrates a remarkable ability to catalytically divert the course of epoxide to oxetane ring expansion via reaction with a sulfoxonium ylide. An expanded survey of transition-metal catalysts has confirmed that cobalt salts uniquely instead… read more here.
Keywords: ring opening; influence cobalt; cobalt; epoxide ring ... See more keywords