Remote Catalytic C(sp3)-H Alkylation via Relayed Carbenoid Transfer upon Olefin Chain Walking.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c11014
Abstract: Transition metal carbenes have emerged as versatile intermediates for various types of alkylations. While reactions of metal carbene species with alkenes have been extensively studied, most examples focus on cyclopropanation and allylic C-H insertion. Herein,… read more here.
Keywords: alkylation; chain walking; olefin chain; remote catalytic ... See more keywords
Recent advances in the remote catalytic functionalisation of ferrocenes.
Sign Up to like & getrecommendations! Published in 2024 at "Dalton transactions"
DOI: 10.1039/d4dt02246g
Abstract: While the catalytic activation of C-H bonds adjacent to a directing group is well developed in the ferrocene series, the functionalisation of a remote position has scarcely been explored. Here, we summarise the latest developments… read more here.
Keywords: advances remote; catalytic functionalisation; functionalisation ferrocenes; functionalisation ... See more keywords