Isomeric Imidazopyridine-Based NHC Ligands: Enhanced Catalytic Activity of an Electron-Donating Remote NHC in a PEPPSI-Type Palladium Complex
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DOI: 10.1021/acsomega.5c10321
Abstract: We report the synthesis and characterization of a new series of imidazopyridine-based N-heterocyclic carbene (NHC) ligands, including three unique binding modes: less atom-stabilized (C5-bound), remote normal (C7-bound), and remote mesoionic (C8-bound) configurations. These distinct ligands… read more here.
Keywords: electron donating; nhc ligands; imidazopyridine based; remote nhc ... See more keywords