Reorganization Energies for Interfacial Proton-Coupled Electron Transfer to a Water Oxidation Catalyst.
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DOI: 10.1021/jacs.2c09672
Abstract: The reorganization energy (λ) for interfacial electron transfer (ET) and proton-coupled ET (PCET) from a conductive metal oxide (In2O3:Sn, ITO) to a surface-bound water oxidation catalyst was extracted from kinetic data measured as a function… read more here.
Keywords: reorganization; water oxidation; electron; reorganization energy ... See more keywords
Heterogeneous electron transfer reorganization energy at the inner Helmholtz plane in a polybromide redox-active ionic liquid
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DOI: 10.1039/d2sc01410f
Abstract: In ionic liquids (ILs), the electric double layer (EDL) is where heterogeneous electron transfer (ET) occurs. Nevertheless, the relationship between the EDL structure and its kinetics has been rarely studied, especially for ET taking place… read more here.
Keywords: electron transfer; reorganization; reorganization energy;
Reducing the internal reorganization energy via symmetry controlled π-electron delocalization
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DOI: 10.1039/d2sc01851a
Abstract: The magnitude of the reorganization energy is closely related to the nonradiative relaxation rate, which affects the photoemission quantum efficiency, particularly for the emission with a lower energy gap toward the near IR (NIR) region.… read more here.
Keywords: delocalization; reorganization; energy; reducing internal ... See more keywords