Asymmetric Dihydroxylation-Based Kinetic Resolution of Allylic Amides Enabled by Noncovalent π-Interactions.
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DOI: 10.1021/acs.orglett.2c03486
Abstract: While Sharpless asymmetric dihydroxylation is widely utilized to convert various alkenes into diols with excellent enantioselectivies, kinetic resolution by means of this fundamental catalysis has generally proven to be ineffective. Here we report that, by… read more here.
Keywords: based kinetic; noncovalent interactions; resolution; asymmetric dihydroxylation ... See more keywords