Oxidative kinetic resolution of P-chiral phosphines catalyzed by chiral (salen)dioxomolybdenum complexes
Sign Up to like & getrecommendations! Published in 2021 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2021.111776
Abstract: Abstract Synthetic LMoO2 compounds have long been of keen interest both as structural and functional models for molybdoenzymes and in their own right as catalysts for a variety of oxygen atom-transfer (OAT) reactions. Investigations of… read more here.
Keywords: chiral salen; oxidative kinetic; resolution chiral; kinetic resolution ... See more keywords
Enzymatic kinetic resolution of chiral sulfoxides - an enantiocomplementary approach.
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DOI: 10.1039/c9cc05470g
Abstract: A new enzymatic assay for the preparation of chiral sulfoxides that is enantiocomplementary to the known (S)-enantiomer-reducing activity of methionine sulfoxide reductase A (MsrA) is described. To this end, we have utilized the enzyme DMSO… read more here.
Keywords: sulfoxides enantiocomplementary; chiral sulfoxides; enantiocomplementary approach; kinetic resolution ... See more keywords
Intensification of Double Kinetic Resolution of Chiral Amines and Alcohols via Chemoselective Formation of a Carbonate–Enzyme Intermediate
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DOI: 10.3390/molecules27144346
Abstract: Chiral amines and alcohols are synthons of numerous pharmaceutically-relevant compounds. The previously developed enzymatic kinetic resolution approaches utilize a chiral racemic molecule and achiral acyl donor (or acyl acceptor). Thus, only one enantiodivergent step of… read more here.
Keywords: amines alcohols; resolution; chiral amines; enzyme ... See more keywords