Resolving Conflicting Mechanisms for Photoredox Allylic sp3-CH Arylation Using Deuterium-Labeling and Isotope Effects.
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DOI: 10.1021/acscatal.4c01645
Abstract: Two conflicting mechanisms have emerged for the direct arylation of allylic C-H bonds enabled by the combined use of thiol and photoredox catalysis. In the original report (Nature, 2015, 519, 74-77), a radical coupling step-between… read more here.
Keywords: radical anion; resolving conflicting; mechanisms photoredox; radical coupling ... See more keywords