Probing the Strong Nonadiabatic Interactions in the Triazolyl Radical Using Photodetachment Spectroscopy and Resonant Photoelectron Imaging of Cryogenically Cooled Anions.
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DOI: 10.1021/jacs.2c07167
Abstract: Although the adiabatic potential energy surfaces defined by the Born-Oppenheimer approximation are the cornerstones for understanding the electronic structure and spectroscopy of molecular systems, nonadiabatic effects due to the coupling of electronic states by nuclear… read more here.
Keywords: photoelectron imaging; resonant photoelectron; photodetachment spectroscopy; spectroscopy ... See more keywords