Stereoselective allylic reduction via one-pot palladium-catalyzed allylic sulfonation and sulfinyl retro-ene reactions
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DOI: 10.1039/c8qo00233a
Abstract: A tandem approach for the stereoselective allylic reduction has been developed based on a strategy combining the palladium-catalyzed S-allylation and the sulfinyl retro-ene reactions. In a one-pot process employing various allylic carbonates, sodium t-butyldimethylsilyloxymethanesulfinate (TBSOMS-Na),… read more here.
Keywords: retro ene; allylic reduction; ene reactions; sulfinyl retro ... See more keywords