Articles with "reverse micelles" as a keyword



Formation of Phospholipid Association Colloids in Rapeseed Oil and Their Effect on Lipid Autoxidation in the Presence of Sinapic and Ferulic Acid

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Published in 2019 at "European Journal of Lipid Science and Technology"

DOI: 10.1002/ejlt.201900243

Abstract: This study describes the formation of 1,2‐dioleoyl‐sn‐glycero‐3‐phosphocholine (DOPC) association colloids (reverse micelles) in rapeseed oil and interactions of sinapic and ferulic acids with these structures. Furthermore, the process of oil autoxidation in the presence of… read more here.

Keywords: rapeseed oil; presence; formation; oil ... See more keywords

Determination of the Water/AOT/Isooctane Reverse Micelles Size Parameters from Their Refractive Index Data

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Published in 2017 at "Journal of Solution Chemistry"

DOI: 10.1007/s10953-016-0563-x

Abstract: The present paper aims to study the proprieties of water confined in water/AOT/isooctane reverse micelles from their refractive indices at 298.5 K. The refractive indices of the microemulsions were investigated at increasing water concentration and at… read more here.

Keywords: water aot; water; reverse micelles; refractive index ... See more keywords

Self – assembly of model surfactants as reverse micelles in nonpolar solvents and their role as interfacial tension modifiers

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Published in 2021 at "Colloids and Surfaces A: Physicochemical and Engineering Aspects"

DOI: 10.1016/j.colsurfa.2021.126244

Abstract: Abstract The self-assembly of linear surfactants into reverse micelles (RMs) in nonpolar solvents, and their efficiency in reducing the interfacial tension is studied using dissipative particle dynamic simulations. Given the importance of RMs as thickeners,… read more here.

Keywords: self assembly; interfacial tension; surfactants reverse; tension ... See more keywords

Imim-DEHP reverse micelles investigated with two molecular probes reveals how are the interfacial properties and the coordination behavior of the surfactant

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Published in 2020 at "Journal of Molecular Liquids"

DOI: 10.1016/j.molliq.2020.113592

Abstract: Abstract Aqueous reverse micelles (RMs) generated with the ionic liquid (IL)-surfactant 1-methylimidazolium bis-(2-ethylhexyl)phosphate (imim-DEHP) and the biocompatible solvents methyl laurate (ML) and isopropyl myristate (IPM) were studied through the use of two molecular probes: the… read more here.

Keywords: dehp; two molecular; imim dehp; molecular probes ... See more keywords
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How mobile is the water in the reverse micelles? A 2DIR study with an ultrasmall IR probe

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Published in 2020 at "Journal of Molecular Liquids"

DOI: 10.1016/j.molliq.2020.114819

Abstract: Abstract Water molecules in reverse micelle serve as an excellent model for biological water. However, it has been argued previously that water molecules at the centre, even for smaller sized water pools of reverse micelles,… read more here.

Keywords: probe; water; water pool; vibrational lifetime ... See more keywords
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Laser diagnostics of reverse microemulsions: Influence of the size and shape of reverse micelles on the Raman spectrum on the example of water/AOT/cyclohexane system

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Published in 2021 at "Journal of Molecular Liquids"

DOI: 10.1016/j.molliq.2020.115153

Abstract: Abstract In this study, the influence of the size and shape of reverse micelles in water/AOT-Na/cyclohexane microemulsions on the spectral characteristics of vibrational spectra was studied using Raman laser spectroscopy and method of dynamic light… read more here.

Keywords: water; size; influence size; size shape ... See more keywords

Ascorbyl radical disproportionation in reverse micellar systems

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Published in 2017 at "Radiation Physics and Chemistry"

DOI: 10.1016/j.radphyschem.2017.10.019

Abstract: Abstract Ascorbyl radical was generated by the pulse radiolysis method and observed with the fast kinetic spectrophotometry within reverse micelles stabilized by AOT in n-heptane or by Igepal CO-520 in cyclohexane at different water to… read more here.

Keywords: ascorbyl radical; reverse micellar; reverse; aot heptane ... See more keywords

Ultrafast Fluorescence Dynamics of Highly Stable Copper Nanoclusters Synthesized inside the Aqueous Nanopool of Reverse Micelles

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Published in 2018 at "Journal of Physical Chemistry C"

DOI: 10.1021/acs.jpcc.7b11457

Abstract: Herein, we have reported a new strategy for the synthesis of highly stable fluorescent copper nanoclusters (CuNCs) with l-cysteine (Cys) as a protecting ligand within the water nanopool of reverse micelles (RMs). In the present… read more here.

Keywords: surface states; fluorescence; nanopool reverse; copper nanoclusters ... See more keywords

Parahydrogen Polarization in Reverse Micelles and Application to Sensing of Protein–Ligand Binding

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Published in 2024 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.4c13177

Abstract: A medium containing reverse micelles supports non-hydrogenative parahydrogen induced polarization (nhPHIP) in the organic phase while solubilizing a protein in the aqueous phase. Strongly enhanced NMR signals from iridium hydride complexes report on a ligand,… read more here.

Keywords: parahydrogen; polarization reverse; parahydrogen polarization; reverse micelles ... See more keywords

Alginate nanoparticle synthesis using n-heptane and isopropyl myristate/AOT reverse micelles: the impact of the non-polar solvent, water content, and pH on the particle size and cross-linking efficiency

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Published in 2024 at "New Journal of Chemistry"

DOI: 10.1039/d4nj02981j

Abstract: The synthesis of monodisperse and stable alginate nanoparticles (ALG-NPs) was achieved through the crosslinking of sodium alginate with Ca2+ ions within sodium bis(2-ethylhexyl)sulfosuccinate (AOT) reverse micelles (RMs) as nano-templates. read more here.

Keywords: alginate nanoparticle; synthesis; reverse micelles; aot reverse ... See more keywords

Compositional versatility enables biologically inspired reverse micelles for study of protein–membrane interactions

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Published in 2025 at "Soft Matter"

DOI: 10.1039/d5sm00033e

Abstract: The study of membranes and their associated proteins is critical for understanding cellular processes. In vitro investigations utilizing membrane models often have limitations in their biological relevance due to the dissimilarity of experimentally compatible membrane… read more here.

Keywords: biologically inspired; compositional versatility; enables biologically; protein ... See more keywords