Construction of Vicinal Quaternary Carbon Centers via Cobalt-Catalyzed Asymmetric Reverse Prenylation.
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DOI: 10.1021/acs.orglett.8b04030
Abstract: A highly enantioselective cobalt-catalyzed reverse prenylation of β-ketoester with tertiary allylic carbonate to construct vicinal all-carbon quaternary carbon centers has been developed. By using the cobalt/( S, S)Ph-BPE complex generated in situ with zinc reduction,… read more here.
Keywords: carbon; cobalt; reverse prenylation; carbon centers ... See more keywords