Rational design of FLP catalysts for reversible H 2 activation: A DFT study of the geometric and electronic effects
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DOI: 10.1016/j.cclet.2018.02.007
Abstract: Abstract Frustrated Lewis pairs (FLPs) emerge as a new type of bifunctional metal-free catalysts for reversible H2 activation, which is important for the storage and liberation of H2 or further controllable utilizing chemical fuels via… read more here.
Keywords: reversible activation; rational design; dft study; activation ... See more keywords
The Role of Proton Shuttles in the Reversible Activation of Hydrogen via Metal-Ligand Cooperation.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b09062
Abstract: The reversible activation of H2 via a pathway involving metal-ligand cooperation (MLC) is proposed to be important in many transition metal catalyzed hydrogenation and dehydrogenation reactions. Nevertheless, there is a paucity of experimental information probing… read more here.
Keywords: reversible activation; metal; proton shuttles; metal ligand ... See more keywords