Reversible addition–fragmentation chain transfer (co)polymerization of conjugated diene monomers: butadiene, isoprene and chloroprene
Sign Up to like & getrecommendations! Published in 2017 at "Polymer International"
DOI: 10.1002/pi.5173
Abstract: This review provides a critical survey of the literature on reversible addition–fragmentation chain transfer (RAFT) (co)polymerization of industrially significant conjugated diene monomers, specifically butadiene, isoprene and chloroprene. There is a focus on polymerizations performed in… read more here.
Keywords: fragmentation chain; polymerization; conjugated diene; addition fragmentation ... See more keywords
Ultrasensitive Impedimetric Immunosensor for the Detection of C-Reactive Protein in Blood at Surface-Initiated-Reversible Addition–Fragmentation Chain Transfer Generated Poly(2-hydroxyethyl methacrylate) Brushes
Sign Up to like & getrecommendations! Published in 2020 at "Analytical Chemistry"
DOI: 10.1021/acs.analchem.9b05030
Abstract: The reversible addition-fragmentation chain transfer (RAFT) polymerization of 2-hydroxethyl methacrylate (HEMA) from a surface confined, dithio-tethered, chain transfer agent (CTA) enables the preparation of electrode-tethered poly(2-hydroxyethyl methacrylate) (pHEMA) brushes of well-defined thickness with convenience and… read more here.
Keywords: chain; methacrylate; chain transfer; reversible addition ... See more keywords
Glycosylated Reversible Addition-Fragmentation Chain Transfer Polymers with Varying Polyethylene Glycol Linkers Produce Different Short Interfering RNA Uptake, Gene Silencing, and Toxicity Profiles.
Sign Up to like & getrecommendations! Published in 2017 at "Biomacromolecules"
DOI: 10.1021/acs.biomac.7b01168
Abstract: Achieving efficient and targeted delivery of short interfering (siRNA) is an important research challenge to overcome to render highly promising siRNA therapies clinically successful. Challenges exist in designing synthetic carriers for these RNAi constructs that… read more here.
Keywords: fragmentation chain; short interfering; addition fragmentation; gene silencing ... See more keywords
Highly Efficient Selective Extraction of Chlorpyrifos Residues from Apples by Magnetic Microporous Molecularly Imprinted Polymer Prepared by Reversible Addition-Fragmentation Chain Transfer Surface Polymerization.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of agricultural and food chemistry"
DOI: 10.1021/acs.jafc.2c06236
Abstract: Chlorpyrifos, as a moderate toxic organophosphorus pesticide, is prone to lingering in the environment and cannot be monitored easily. In this study, a magnetic, microporous, molecularly imprinted polymer was synthesized by using the reversible addition-fragmentation… read more here.
Keywords: microporous molecularly; molecularly imprinted; magnetic microporous; imprinted polymer ... See more keywords
Toward Electrochemically Mediated Reversible Addition–Fragmentation Chain-Transfer (eRAFT) Polymerization: Can Propagating Radicals Be Efficiently Electrogenerated from RAFT Agents?
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecules"
DOI: 10.1021/acs.macromol.9b00112
Abstract: Electrochemistry provides easily tunable parameters for the preparation of well-defined polymers in a spatiotemporal controlled manner under mild conditions. This work discusses the requisites for an electrochemically mediated reversible addition–fragmentation chain-transfer (eRAFT) polymerization, in which… read more here.
Keywords: raft; electrochemically mediated; mediated reversible; reversible addition ... See more keywords
Synthesis and Reactivity of Group Six Metal PCP Pincer Complexes: Reversible CO Addition Across the Metal–Caryl Bond
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00447
Abstract: In the present study, Cr(III) complexes of the type trans-[Cr(PCPNEt-iPr)(solvent)Cl2] (solvent = CH3CN, THF), the Cr(0) complex [Cr(κ3P,CH,P-P(CH)PNEt-iPr)(CO)3] which features an η2-Caryl–H agostic bond as well as seven coordinate cationic chloro carbonyl Mo(II) and W(II)… read more here.
Keywords: pcpnet ipr; bond; across metal; metal ... See more keywords
Synthesis of PNVP-Based Copolymers with Tunable Thermosensitivity by Sequential Reversible Addition–Fragmentation Chain Transfer Copolymerization and Ring-Opening Polymerization
Sign Up to like & getrecommendations! Published in 2017 at "Polymers"
DOI: 10.3390/polym9060231
Abstract: Through the reversible addition–fragmentation chain transfer (RAFT) copolymerization of 3-ethyl-1-vinyl-2-pyrrolidone (C2NVP) and N-vinylpyrrolidone (NVP), a series of well-defined P(C2NVP-co-NVP) copolymers were synthesized (Mn = ca. 8000 to 16,000 and Mw/Mn read more here.
Keywords: chain; c2nvp; addition fragmentation; reversible addition ... See more keywords