Conversion of Dinitrogen and Oxygen to Nitric Oxide Mediated by Triatomic Yttrium Cations: Reversible N-N Bond Switching.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00092
Abstract: The direct coupling of dinitrogen (N2) and oxygen (O2) to produce value-added chemicals such as nitric acid (HNO3) at room temperature is fascinating but quite challenging because of the inertness of N2 molecules. Herein, an… read more here.
Keywords: reversible bond; bond switching; dinitrogen oxygen; bond ... See more keywords
Reversible C–N Bond Formation in the Zirconium-Catalyzed Intermolecular Hydroamination of 2-Vinylpyridine
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00904
Abstract: The intermolecular hydroamination of alkenes with alkylamines has been a long-standing challenge in catalysis, partially due to the near-thermoneutral nature of this transformation. Consistent with this understanding, we report the direct observation of reversible C–N… read more here.
Keywords: bond formation; hydroamination; intermolecular hydroamination; reversible bond ... See more keywords
Reversible C–C bond formation using palladium catalysis
Sign Up to like & getrecommendations! Published in 2022 at "Nature Chemistry"
DOI: 10.1038/s41557-022-00898-0
Abstract: A widely appreciated principle is that all reactions are fundamentally reversible. Observing reversible transition metal-catalysed reactions, particularly those that include the cleavage of C–C bonds, is more challenging. The development of palladium- and nickel-catalysed carboiodination… read more here.
Keywords: formation using; bond formation; bond; reversible bond ... See more keywords
Reversible P-P bond cleavage at an iridium(III) metal centre.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00706a
Abstract: Treatment of a κ1-P-monodentate bicyclic diphosphane iridium(III) complex with a labile gold(I) precursor afforded an unusual IrIII/AuI complex in which the P-P single bond has been cleaved. This reaction was cleanly reversed upon addition of… read more here.
Keywords: iridium iii; reversible bond; bond cleavage; bond ... See more keywords