Air-tolerant Reversible Complexation Mediated Polymerization (RCMP) Using Aldehyde as Oxygen Removera.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200091
Abstract: An air-tolerant reversible complexation mediated polymerization (RCMP) technique, which can be carried out without prior deoxygenation, was developed. The system contains a monomer, an alkyl iodide initiating dormant species, air (oxygen), an aldehyde, N-hydroxyphthalimide (NHPI),… read more here.
Keywords: reversible complexation; air; rcmp; tolerant reversible ... See more keywords
Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process
Sign Up to like & getrecommendations! Published in 2022 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.2c00004
Abstract: A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques—reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes—is reported. First, RCMP… read more here.
Keywords: reversible complexation; block copolymers; mediated living; complexation mediated ... See more keywords
Self-condensing reversible complexation-mediated copolymerization for highly branched polymers with in situ formed inimers
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DOI: 10.1039/c7py01560g
Abstract: In this work, reversible complexation-mediated polymerization (RCMP) was modified to suit self-condensing vinyl polymerization (SCVP) aimed at the synthesis of highly branched polymers. For this purpose, two azo-containing pre-inimers with divinyl (DMACPO) or monovinyl (MACPO)… read more here.
Keywords: complexation mediated; polymerization; self condensing; reversible complexation ... See more keywords
Synthesis of transition-metal-free and sulfur-free nanoparticles and nanocapsules via reversible complexation mediated polymerization (RCMP) and polymerization induced self-assembly (PISA)
Sign Up to like & getrecommendations! Published in 2018 at "Polymer Chemistry"
DOI: 10.1039/c8py01117f
Abstract: NaI-catalyzed reversible complexation mediated living radical polymerization (RCMP) was combined with polymerization induced self-assembly (PISA) to generate self-assemblies. Poly(methacrylic acid) (PMAA) and poly(methyl methacrylate) (PMMA) were used as hydrophilic and hydrophobic segments, respectively, to generate… read more here.
Keywords: complexation mediated; polymerization; reversible complexation; self ... See more keywords