Articles with "reversible complexation" as a keyword



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Air-tolerant Reversible Complexation Mediated Polymerization (RCMP) Using Aldehyde as Oxygen Removera.

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Published in 2022 at "Macromolecular rapid communications"

DOI: 10.1002/marc.202200091

Abstract: An air-tolerant reversible complexation mediated polymerization (RCMP) technique, which can be carried out without prior deoxygenation, was developed. The system contains a monomer, an alkyl iodide initiating dormant species, air (oxygen), an aldehyde, N-hydroxyphthalimide (NHPI),… read more here.

Keywords: reversible complexation; air; rcmp; tolerant reversible ... See more keywords
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Synthesis of Block Copolymers by Mechanistic Transformation from Reversible Complexation Mediated Living Radical Polymerization to the Photoinduced Radical Oxidation/Addition/Deactivation Process

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Published in 2022 at "ACS Macro Letters"

DOI: 10.1021/acsmacrolett.2c00004

Abstract: A versatile strategy for the fabrication of block copolymers by the combination of two discrete living polymerization techniques—reversible complexation mediated living radical polymerization (RCMP) and photoinduced radical oxidation addition deactivation (PROAD) processes—is reported. First, RCMP… read more here.

Keywords: reversible complexation; block copolymers; mediated living; complexation mediated ... See more keywords
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Self-condensing reversible complexation-mediated copolymerization for highly branched polymers with in situ formed inimers

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Published in 2017 at "Polymer Chemistry"

DOI: 10.1039/c7py01560g

Abstract: In this work, reversible complexation-mediated polymerization (RCMP) was modified to suit self-condensing vinyl polymerization (SCVP) aimed at the synthesis of highly branched polymers. For this purpose, two azo-containing pre-inimers with divinyl (DMACPO) or monovinyl (MACPO)… read more here.

Keywords: complexation mediated; polymerization; self condensing; reversible complexation ... See more keywords
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Synthesis of transition-metal-free and sulfur-free nanoparticles and nanocapsules via reversible complexation mediated polymerization (RCMP) and polymerization induced self-assembly (PISA)

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Published in 2018 at "Polymer Chemistry"

DOI: 10.1039/c8py01117f

Abstract: NaI-catalyzed reversible complexation mediated living radical polymerization (RCMP) was combined with polymerization induced self-assembly (PISA) to generate self-assemblies. Poly(methacrylic acid) (PMAA) and poly(methyl methacrylate) (PMMA) were used as hydrophilic and hydrophobic segments, respectively, to generate… read more here.

Keywords: complexation mediated; polymerization; reversible complexation; self ... See more keywords