Reversible Redox‐Driven Crystallization in a Paracyclophane Monolayer at a Solid–Liquid Interface
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202315861
Abstract: The development and integration of cyclophanes into future functional materials require a detailed understanding of the physicochemical principles that underlie their properties, phase behavior, and in particular the relationship between structure and function. Here, electrochemically… read more here.
Keywords: redox driven; crystallization paracyclophane; crystallization; driven crystallization ... See more keywords
Analysis of voltammograms of quasi-reversible redox systems: Transformation to potential program invariant form
Sign Up to like & getrecommendations! Published in 2019 at "Electrochimica Acta"
DOI: 10.1016/j.electacta.2018.12.023
Abstract: Abstract A simple procedure has recently been suggested (T. Pajkossy, Electrochem. Comm. 90 (2018) 69) by which various types of voltammograms, above all cyclic voltammograms, pertaining to partially diffusion controlled charge transfer reactions can be… read more here.
Keywords: reversible redox; form; quasi reversible; voltammograms quasi ... See more keywords
Reversible Redox Chemistry of Anionic Imidazole-2-thione-Fused 1,4-Dihydro-1,4-diphosphinines
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.1c03620
Abstract: Anionic 1,4-dihydro-1,4-diphosphinines were synthesized from tricyclic 1,4-diphosphinines and isolated as blue powdery salts M[2a–2c]. Reaction of solutions of these monoanions with iodomethane led to P-methylated compounds 3a–3c. An oxidation/reduction cycle was examined, starting from solutions… read more here.
Keywords: anionic imidazole; chemistry anionic; chemistry; reversible redox ... See more keywords
Reversible Redox Ligand-Centered Reactivity in 2,6-Bisiminopyridine Aluminum Systems
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.4c02664
Abstract: We report the synthesis of cationic 2,6-bisiminopyridine organoaluminum complexes, [(BIP)AlR2]+, as stable BArF4– or PF6– salts, and their reversible single-electron reduction into well-defined paramagnetic species, [(BIP·)AlR2]. Four redox couples, [(BIP)AlR2]+/0, have been fully characterized through… read more here.
Keywords: bisiminopyridine; redox ligand; ligand centered; bip alr2 ... See more keywords
Aminotroponiminates: ligand-centred, reversible redox events under oxidative conditions in sodium and bismuth complexes.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt01019f
Abstract: A straightforward synthetic route to aminotroponate (AT) and aminotroponiminate (ATI) ligands with a ferrocenyl substituent at nitrogen is presented. Sodium derivatives have been synthesised and the first synthetic access to bismuth AT and ATI species… read more here.
Keywords: ligand centred; centred reversible; aminotroponiminates ligand; bismuth ... See more keywords
Evidence of a reversible redox reaction in a liquid-electrolyte-type fluoride-ion battery
Sign Up to like & getrecommendations! Published in 2022 at "RSC Advances"
DOI: 10.1039/d2ra05753k
Abstract: Fluoride-ion batteries (FIBs) have received significant attention as promising alternatives to conventional lithium-ion batteries, but a reversible redox reaction has not been confirmed yet for liquid-electrolyte-type FIBs. We conducted ex situ X-ray diffraction and energy… read more here.
Keywords: reaction; electrolyte type; redox reaction; reversible redox ... See more keywords