Structure and Mechanism Revision of a Catalyzed Cyclization of Benzaldehyde Bearing Alkyne-Nitrile.
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DOI: 10.1021/acs.orglett.7b01881
Abstract: Pt(II)-catalyzed carbocyclization of benzaldehyde containing a keto-nitrile functionality resulted in the formation, respectively, of isochromenes and spiro-lactones instead of fused lactams and spiro-lactams as was previously reported. The reaction mechanism was proposed, and the products… read more here.
Keywords: structure mechanism; benzaldehyde; revision catalyzed; mechanism ... See more keywords