Atomically Precise Rhodium‐Gold Carbonyl Nanoclusters: In‐Depth Synthesis and Multivalence Investigation of [Rh16Au6(CO)36]6‐, and its Correlation with [Rh10Au(CO)26]3‐.
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DOI: 10.1002/ejic.202400526
Abstract: The synthesis of the previously‐reported atomically‐precise [Rh16Au6(CO)36]6‐ (1) nanocluster has been optimized by screening different reaction variables like solvent, stoichiometric ratio, counterion and atmosphere. Its multivalence properties have also been studied by means of electrochemical… read more here.
Keywords: rh10au; rh16au6; multivalence; investigation ... See more keywords