Luminescent rhenium(I) carbonyl complex with redox noninnocent ONS donor azo-phenol ligand: Synthesis, X-ray structure, photophysical properties and live cell imaging
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.01.004
Abstract: Abstract Herein, we have synthesized a new fluorescent rhenium(I) carbonyl complex 1, bearing {Re(CO)3}+ core with ONS donor thioether containing azo-phenol redox noninnocent ligand. The distorted octahedral geometry of the complex is confirmed by single… read more here.
Keywords: redox noninnocent; rhenium carbonyl; carbonyl complex; azo phenol ... See more keywords
Rhenium Carbonyl Molecular Catalysts for CO2 Electroreduction: Effects on Catalysis of Bipyridine Substituents Mimicking Anchorage Functions to Modify Electrodes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02473
Abstract: Heterogenization of molecular catalysts on (photo)electrode surfaces is required to design devices performing processes enabling to store renewable energy in chemical bonds. Among the various strategies to immobilize molecular catalysts, direct chemical bonding to conductive… read more here.
Keywords: catalyst; carbonyl molecular; rhenium carbonyl; co2 electroreduction ... See more keywords
Molecular engineered rhenium(i) carbonyl complexes to promote photoisomerization of coordinated stilbene-like ligands in the visible region.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt02721h
Abstract: Novel fac-[Re(CO)3(dmcb)(trans-stpyR)]+ complexes, dmcb = 4,4'-dimethoxycarbonyl-2,2'-bipyridine, have been judiciously engineered to absorb at lower energies and sensitize trans-4-styrylpyridine (trans-stpy) or trans-4-(4-cyano)styrylpyridine (trans-stpyCN) photoisomerizable ligands up to 436 nm of irradiation. Moreover, these complexes exhibit remarkable… read more here.
Keywords: stilbene like; molecular engineered; rhenium carbonyl; engineered rhenium ... See more keywords