Phosphorescent rhenium(I) complexes conjugated with artesunate: Mitochondrial targeting and apoptosis-ferroptosis dual induction.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2021.111537
Abstract: Cell death is essential for cancer, which can be induced through multiple mechanisms. Ferroptosis, a newly emerging form of non-apoptotic cell death, involves the generation of iron-dependent reactive oxygen species (ROS). In this study, we… read more here.
Keywords: rhenium complexes; ferroptosis; art; phosphorescent rhenium ... See more keywords
Diastereomeric Separation of Chiral fac-Tricarbonyl(iminopyridine) Rhenium(I) Complexes and Their Cytotoxicity Studies: Approach toward an Action Mechanism against Glioblastoma.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of medicinal chemistry"
DOI: 10.1021/acs.jmedchem.2c00561
Abstract: A series of new (tricarbonyl)rhenium(I) complexes were synthesized using chiral bidentate ligands (+)/(-)-iminopyridines (LR/LS). The reaction yielded a mixture of mononuclear Re(I) diastereoisomers, formulated as fac-[Br(CO)3Re(S/R)L(S/R)]. Each single diastereoisomer was isolated and fully characterized. X-ray… read more here.
Keywords: glioblastoma; cytotoxicity; rhenium complexes; separation chiral ... See more keywords
Rhenium Complexes Bearing Tridentate and Bidentate Phosphinoamine Ligands in the Production of Biofuel Alcohols via the Guerbet Reaction
Sign Up to like & getrecommendations! Published in 2021 at "Organometallics"
DOI: 10.1021/acs.organomet.1c00313
Abstract: We report a variety of rhenium complexes supported by bidentate and tridentate phosphinoamine ligands and their use in the formation of the advanced biofuel isobutanol from methanol and ethanol. Rhenium pincer complexes 1–3 are effective… read more here.
Keywords: rhenium complexes; tridentate; bidentate phosphinoamine; rhenium ... See more keywords
Synthesis, structures and catalytic activity of cyclometalated rhenium complexes
Sign Up to like & getrecommendations! Published in 2017 at "RSC Advances"
DOI: 10.1039/c6ra28263f
Abstract: Thermal reactions of aryl-substituted phosphines or phosphinites with Re2(CO)10 in chlorobenzene resulted in the corresponding five-membered cyclometalated rhenium complexes (1–5) via an intramolecular activation of the C(sp2)–H or C(sp3)–H bond. The only exception occurred in… read more here.
Keywords: rhenium complexes; structures catalytic; synthesis structures; bond ... See more keywords
Supramolecular structures of rhenium(I) complexes mediated by ligand planarity via the interplay of substituents.
Sign Up to like & getrecommendations! Published in 2018 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229618010586
Abstract: The crystal and molecular structures of two ReI tricarbonyl complexes, namely fac-tricarbonylchlorido[1-(4-fluorocinnamoyl)-3-(pyridin-2-yl-κN)pyrazole-κN2]rhenium(I), [ReCl(C17H12FN3O)(CO)3], (I), and fac-tricarbonylchlorido[1-(4-nitrocinnamoyl)-3-(pyridin-2-yl-κN)pyrazole-κN2]rhenium(I) acetone monosolvate, [ReCl(C17H12ClN4O3)(CO)3]·C3H6O, (II), are reported. The complexes form centrosymmetric dimers that are linked into one-dimensional columns by C-H...Cl… read more here.
Keywords: rhenium complexes; planarity; mediated ligand; complexes mediated ... See more keywords