Synthesis and Catalytic Applications of Heterobimetallic Carbene Complexes Obtained via Sequential Metalation of Two Bisazolium Salts
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00120
Abstract: A simple sequential metalation approach starting from the imidazolium/benzimidazolium salt 4(I)2 yielded the heterobimetallic RhIII/M (M = PdII, IrI, AuI, RuII) complexes [6]–[9]. Alternatively, a symmetrical 1,3-imidazolium substituted benzene was used for the preparation of… read more here.
Keywords: catalytic applications; sequential metalation; bisazolium; synthesis catalytic ... See more keywords
Metal-ligand cooperative κ1-N-pyrazolate Cp*RhIII-catalysts for dehydrogenation of dimethylamine-borane at room temperature.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt01705e
Abstract: 3,5-Dimethylpyrazole (Pz*H) in well-defined Cp*RhIII (Cp* = 1,2,3,4,5-pentamethylcyclopentadienyl) complexes, or as an additive to [Cp*RhCl2]2 enhances catalytic activity in the dehydrogenation of dimethylamine-borane (DMAB) at room-temperature. Mechanistic studies indicate that the Lewis acidic RhIII-centre and… read more here.
Keywords: rhiii; borane; dimethylamine borane; room temperature ... See more keywords
Electrochemical Properties of a Rhodium(III) Mono-Terpyridyl Complex and Use as a Catalyst for Light-Driven Hydrogen Evolution in Water
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27196614
Abstract: Molecular hydrogen (H2) is considered one of the most promising fuels to decarbonize the industrial and transportation sectors, and its photocatalytic production from molecular catalysts is a research field that is still abounding. The search… read more here.
Keywords: catalyst light; catalyst; rhiii; mono terpyridyl ... See more keywords