Insights into the ligand effects of rhodium catalysts toward reductive carbonylation of methanol to ethanol
Sign Up to like & getrecommendations! Published in 2017 at "RSC Advances"
DOI: 10.1039/c7ra10739k
Abstract: Methanol reductive carbonylation to ethanol catalyzed by diphosphine ligand modified Rh-based catalysts has been studied. All the catalysts show ligand effects toward the turnover frequency and selectivity. Four Rh–diphosphine complexes were isolated and single crystals… read more here.
Keywords: catalysts toward; ligand effects; reductive carbonylation; effects rhodium ... See more keywords
Rhodium catalysts with superbulky NHC ligands for the selective α-hydrothiolation of alkynes.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00243d
Abstract: Eight rhodium complexes-including four new compounds-with the generic formula [RhCl(cod)(NHC)] (cod is 1,3-cyclooctadiene) differing by the size of their N-heterocyclic carbene (NHC) ligand were prepared, characterized, and found to be catalytically active in the hydrothiolation… read more here.
Keywords: ligands selective; rhodium catalysts; nhc ligands; hydrothiolation ... See more keywords