Fluorene-containing β-diketonato ligands and their Rhodium(I) complexes
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.120209
Abstract: Abstract In this study, the fluorene-group was added to metal complexes, via the easily synthesized β-diketonato ligand. This enables the incorporation of a fluorescent tag into a variety of metal complexes. Three fluorene-containing β-diketones (1–3)… read more here.
Keywords: rhodium; rhodium complexes; diketonato ligands; fluorene containing ... See more keywords
Mitochondrial targeted rhodium(III) complexes: Synthesis, characterized and antitumor mechanism investigation.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2021.111400
Abstract: Recently, rhodium complexes have received intensive attentions due to their tunable chemical and biological properties as well as attractive antitumor activity. In this work, two imidazole triphenylamino rhodium complexes [Rh(ppy)2L1]PF6 (Rh1) and [Rh(ppy)2L2]PF6 (Rh2) (ppy = 2-phenylpyridine,… read more here.
Keywords: mechanism; rhodium; rhodium complexes; targeted rhodium ... See more keywords
Carbonyl o-semiqunonato rhodium complexes with diphosphine ligands. Effect of diphosphine bite angle on reactivity and dynamic processes in their coordination sphere. EPR study
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2017.07.001
Abstract: Abstract The bite angle of chelating diphosphines is often responsible for the activity and the selectivity of rhodium catalysts based on them. The EPR study of the composition and the structure of similar complexes with… read more here.
Keywords: epr study; rhodium; rhodium complexes; coordination sphere ... See more keywords
Rhodium(I) Complexes with Ligands Based on N-Heterocyclic Carbene and Hemilabile Pyridine Donors as Highly E Stereoselective Alkyne Hydrosilylation Catalysts
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00361
Abstract: Cationic rhodium(I) complexes containing picolyl-NHC (NHC = N-heterocyclic carbene) ligands that differ in the substitution at the 6-position of the pyridine donor serve as efficient E-selective alkyne hydrosilylation catalyst precursors. Particularly, when the steric hindrance… read more here.
Keywords: pyridine; rhodium complexes; alkyne hydrosilylation; hydrosilylation ... See more keywords
Indenyl Rhodium Complexes with Arene Ligands: Synthesis and Application for Reductive Amination
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00311
Abstract: An efficient protocol for synthesis of indenyl rhodium complexes with arene ligands has been developed. The hexafluoroantimonate salts [(η5-indenyl)Rh(arene)](SbF6)2 (arene = benzene (2a), o-xylene (2b), mesitylene (2c), durene (2d), hexamethylbenzene (2e), and [2.2]paracyclophane (2g)) were… read more here.
Keywords: indenyl; rhodium complexes; indenyl rhodium; arene ligands ... See more keywords
Preparation of Mixed Bis-N-Heterocyclic Carbene Rhodium(I) Complexes
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27207002
Abstract: A series of mixed bis-NHC rhodium(I) complexes of type RhCl(η2-olefin)(NHC)(NHC’) have been synthesized by a stepwise reaction of [Rh(μ-Cl)(η2-olefin)2]2 with two different NHCs (NHC = N-heterocyclic carbene), in which the steric hindrance of both NHC… read more here.
Keywords: rhodium; rhodium complexes; mixed bis; preparation mixed ... See more keywords