Synthesis and biological studies of ruthenium, rhodium and iridium metal complexes with pyrazole-based ligands displaying unpredicted bonding modes
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.03.037
Abstract: Abstract A series of new mono, di thienyl pyrazole (L1) and bridged furyl pyrazole (L2) complexes of arene ruthenium, rhodium and iridium {arene = benzene, p-cymene and Cp∗} have been synthesized and characterized by spectroscopic techniques. The… read more here.
Keywords: ruthenium rhodium; pyrazole; benzene cymene; arene benzene ... See more keywords
Synthesis, structural and antimicrobial studies of half-sandwich ruthenium, rhodium and iridium complexes containing nitrogen donor Schiff-base ligands
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2019.04.116
Abstract: Abstract Synthesis, characterization and antibacterial activity of p-cymene ruthenium, Cp*rhodium and Cp*iridium metal complexes containing pyridyl azine Schiff base ligands have been described. All the complexes have been characterized by various spectroscopic techniques. Molecular structure… read more here.
Keywords: rhodium iridium; activity; base ligands; schiff base ... See more keywords
Mononuclear Rhodium(II) and Iridium(II) Complexes Supported by Tetradentate Pyridinophane Ligands.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b01619
Abstract: The tetradentate ligands N,N'-dialkyl-2,11-diaza[3,3](2,6)pyridinophane (RN4, where R = Me or tBu) were employed to synthesize and fully characterize [(RN4)MI(COD)]+ complexes (M = Rh or Ir; COD = cyclooctadiene). Interestingly, these complexes exhibit accessible oxidation potentials… read more here.
Keywords: mononuclear rhodium; rhodium; pyridinophane; rhodium iridium ... See more keywords
Rhodium-/Iridium-Catalyzed Hydroamination for the Synthesis of 1,2-, 1,3-, or 1,4-Diamines.
Sign Up to like & getrecommendations! Published in 2022 at "ACS catalysis"
DOI: 10.1021/acscatal.2c01835
Abstract: An Ir-catalyzed regioselective hydroamination of allyl amines using aryl amines and catalyst-controlled regiodivergent hydroamination of allylic and homoallylic amines with aniline nucleophiles are reported. The directed hydroamination reactions afford a variety of 1,2-, 1,3-, and… read more here.
Keywords: hydroamination synthesis; hydroamination; iridium catalyzed; synthesis diamines ... See more keywords
Synthesis and characterization of rhodium, iridium, and palladium complexes of a diarylamido-based PNSb pincer ligand.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt02207k
Abstract: A new diarylmido-based pincer proto ligand (iPrPNHSbPh) with one -PPri2 and one -SbPh2 side donor has been synthesized. Three complexes of its amido form were prepared using standard metalation techniques: (iPrPNSbPh)PdCl, (iPrPNSbPh)RhCO, and (iPrPNSbPh)Ir(COE), where… read more here.
Keywords: pincer; sbph2; characterization rhodium; rhodium iridium ... See more keywords